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The pH of a solution prepared by mixing 45.0 mL of 0.183 M KOH and 35.0 mL of 0.145 M HCl is ________.


A) 1.314
B) 1.403
C) 0.00824
D) 12.597
E) 12.923

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In a solution, when the concentrations of a weak acid and its conjugate base are equal, ________.


A) the system is not at equilibrium
B) the buffering capacity is significantly decreased
C) the -log of the [H+] and the -log of the Ka are equal
D) All of the above are true.

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The solubility of slightly soluble salts containing basic anions is proportional to the pH of the solution.

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The molar solubility of ________ is not affected by the pH of the solution.


A) Na3PO4
B) NaF
C) KNO3
D) AlCl3
E) MnS

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The pH of a solution prepared by mixing 40.0 mL of 0.125 M Mg(OH) 2 and 150.0 mL of 0.125 M HCl is ________.


A) 6.29
B) 4.11
C) 1.14
D) 5.78
E) 1.34

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The Ka of acetic acid is 1.76 × 10-5. The pH of a buffer prepared by combining 15.0 mL of 1.00 M potassium acetate and 50.0 mL of 1.00 M acetic acid is ________.


A) 1.705
B) 0.851
C) 3.406
D) 4.232
E) 2.383

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Of the substances below, ________ will decrease the solubility of Pb(CN) 2 in a saturated solution.


A) Pb(MnO4) 2
B) NaMnO4
C) HMnO4
D) H2O2
E) NaCl

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The addition of hydrofluoric acid and ________ to water produces a buffer solution.


A) HCl
B) NaNO3
C) NaCl
D) NaOH
E) NaBr

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Which one of the following pairs cannot be mixed together to form a buffer solution?


A) C5H5N, C5H5NHCl
B) HC2H3O2, NaOH (C2H3O2- = acetate)
C) KOH, HI
D) NH2CH3, HCl
E) NaClO, HNO3

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For any buffer system, the buffer capacity depends on the amount of acid and base from which the buffer is made.

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What change will be caused by addition of a small amount of HCl to a solution containing fluoride ions and hydrogen fluoride?


A) The concentration of hydronium ions will increase significantly.
B) The concentration of fluoride ions will increase as will the concentration of hydronium ions.
C) The concentration of hydrogen fluoride will decrease and the concentration of fluoride ions will increase.
D) The concentration of fluoride ion will decrease and the concentration of hydrogen fluoride will increase.
E) The fluoride ions will precipitate out of solution as its acid salt.

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A solution containing which one of the following pairs of substances will be a buffer solution?


A) NaI, HI
B) KBr, HBr
C) RbCl, HCl
D) CsF, HF
E) none of the above

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The concentration of iodide ions in a saturated solution of lead (II) iodide is ________ M. The solubility product constant of PbI2 is 1.4 × 10-8.


A) 3.8 × 10-4
B) 3.0 × 10-3
C) 1.5 × 10-3
D) 3.5 × 10-9
E) 1.4 × 10-8

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In which of the following aqueous solutions would you expect AgF to have the lowest solubility?


A) 0.030 M LiF
B) pure water
C) 0.023 M NaF
D) 0.015 M KF
E) 0.0075 M AgNO3

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The pH of a solution prepared by mixing 55.0 mL of 0.183 M KOH and 10.0 mL of 0.145 M HC2H3O2 is ________.


A) 9.97
B) 7.74
C) 0.878
D) 13.122
E) none of the above

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A 25.0 mL sample of 0.150 M hydrazoic acid is titrated with a 0.150 M NaOH solution. What is the pH after 26.0 mL of base is added? The Ka of hydrazoic acid is 1.9 × 10-5.


A) 2.54
B) 11.47
C) 7.00
D) 4.70
E) 4.74

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