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Consider the reaction N2(g)+ 3H2(g) Consider the reaction N<sub>2</sub>(g)+ 3H<sub>2</sub>(g)   <sub> </sub> 2NH<sub>3</sub>(g).If nitrogen is removed from the system at equilibrium, what will happen to the hydrogen (H<sub>2</sub>)concentration? 2NH3(g).If nitrogen is removed from the system at equilibrium, what will happen to the hydrogen (H2)concentration?

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Sodium carbonate, Na2CO3(s) , can be prepared by heating sodium bicarbonate, NaHCO3(s) as shown below. 2NaHCO3(s) Sodium carbonate, Na<sub>2</sub>CO<sub>3</sub>(s) , can be prepared by heating sodium bicarbonate, NaHCO<sub>3</sub>(s) as shown below. 2NaHCO<sub>3</sub>(s)    <sub> </sub> Na<sub>2</sub>CO<sub>3</sub>(s) + CO<sub>2</sub>(g) + H<sub>2</sub>O(g) K<sub>p</sub> = 0.23 at 100ºC If a sample of NaHCO<sub>3</sub> is placed in an evacuated flask and allowed to achieve equilibrium at 100ºC, what will the total gas pressure be? A) 0.46 atm B) 0.96 atm C) 0.23 atm D) 0.48 atm E) 0.11 atm Na2CO3(s) + CO2(g) + H2O(g) Kp = 0.23 at 100ºC If a sample of NaHCO3 is placed in an evacuated flask and allowed to achieve equilibrium at 100ºC, what will the total gas pressure be?


A) 0.46 atm
B) 0.96 atm
C) 0.23 atm
D) 0.48 atm
E) 0.11 atm

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Consider the equilibrium equation C(s)+ H2O(g)  Consider the equilibrium equation C(s)+ H<sub>2</sub>O(g)   <sub> </sub> <sub> </sub>CO(g)+ H<sub>2</sub>(g),  \Delta H = 2296 J.Which way will the reaction shift if the volume of the container is decreased? CO(g)+ H2(g), Δ\Delta H = 2296 J.Which way will the reaction shift if the volume of the container is decreased?

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Towards th...

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Consider the reaction N2(g)+ 3H2(g) Consider the reaction N<sub>2</sub>(g)+ 3H<sub>2</sub>(g)   <sub> </sub> 2NH<sub>3</sub>(g).If nitrogen is added to the system at equilibrium, what will happen to the ammonia concentration? 2NH3(g).If nitrogen is added to the system at equilibrium, what will happen to the ammonia concentration?

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Which of the following rate laws is consistent with the following mechanism? A(g) + B(g)  Which of the following rate laws is consistent with the following mechanism? A(g) + B(g)    <sub> </sub> AB(g) fast equilibrium (K<sub>c1</sub>)  AB(g) + C(g)  \rarr  AC(g) + B(g) slow A) Rate = k[A][B] B) Rate = kK<sub>c1</sub>[A][B][C] C) Rate = k[AC][B]/[AB][C] D) Rate = [AB]/[A][B] E) Rate = K<sub>c1</sub>[AC]/[A][C] AB(g) fast equilibrium (Kc1) AB(g) + C(g) \rarr AC(g) + B(g) slow


A) Rate = k[A][B]
B) Rate = kKc1[A][B][C]
C) Rate = k[AC][B]/[AB][C]
D) Rate = [AB]/[A][B]
E) Rate = Kc1[AC]/[A][C]

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B

Consider this gas phase equilibrium system: PCl5(g)  Consider this gas phase equilibrium system: PCl<sub>5</sub>(g)    <sub> </sub> PCl<sub>3</sub>(g) + Cl<sub>2</sub>(g)  \Delta Hº<sub>rxn</sub> = +87.8 kJ/mol. Which of these statements is false? A) Increasing the system volume shifts the equilibrium to the right. B) Increasing the temperature shifts the equilibrium to the right. C) A catalyst speeds up the approach to equilibrium and shifts the position of equilibrium to the right. D) Decreasing the total pressure of the system shifts the equilibrium to the right. E) Increasing the temperature causes the equilibrium constant to increase. PCl3(g) + Cl2(g) Δ\Deltarxn = +87.8 kJ/mol. Which of these statements is false?


A) Increasing the system volume shifts the equilibrium to the right.
B) Increasing the temperature shifts the equilibrium to the right.
C) A catalyst speeds up the approach to equilibrium and shifts the position of equilibrium to the right.
D) Decreasing the total pressure of the system shifts the equilibrium to the right.
E) Increasing the temperature causes the equilibrium constant to increase.

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For the reaction PCl3(g) + Cl2(g) For the reaction PCl<sub>3</sub>(g) + Cl<sub>2</sub>(g)    <sub> </sub> PCl<sub>5</sub>(g) at a particular temperature, K<sub>c</sub> = 24.3.Suppose a system at that temperature is prepared with [PCl<sub>3</sub>] = 0.10 M, [Cl<sub>2</sub>] = 0.15 M, and [PCl<sub>5</sub>] = 0.60 M.Which of the following is true based on the above? A) Q<sub>c</sub> > K<sub>c</sub>, the reaction proceeds from left to right to reach equilibrium B) Q<sub>c</sub> > K<sub>c</sub>, the reaction proceeds from right to left to reach equilibrium C) Q<sub>c</sub> < K<sub>c</sub>, the reaction proceeds from left to right to reach equilibrium D) Q<sub>c</sub> < K<sub>c</sub>, the reaction proceeds from right to left to reach equilibrium E) Q<sub>c</sub> = K<sub>c</sub>, the reaction is currently at equilibrium PCl5(g) at a particular temperature, Kc = 24.3.Suppose a system at that temperature is prepared with [PCl3] = 0.10 M, [Cl2] = 0.15 M, and [PCl5] = 0.60 M.Which of the following is true based on the above?


A) Qc > Kc, the reaction proceeds from left to right to reach equilibrium
B) Qc > Kc, the reaction proceeds from right to left to reach equilibrium
C) Qc < Kc, the reaction proceeds from left to right to reach equilibrium
D) Qc < Kc, the reaction proceeds from right to left to reach equilibrium
E) Qc = Kc, the reaction is currently at equilibrium

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B

When the following reaction is at equilibrium, which of these relationships is always true? 2NOCl(g) When the following reaction is at equilibrium, which of these relationships is always true? 2NOCl(g)    <sub> </sub> 2NO(g) + Cl<sub>2</sub>(g)  A) [NO] [Cl<sub>2</sub>] = [NOCl] B) [NO]<sup>2</sup> [Cl<sub>2</sub>] = [NOCl]<sup>2</sup> C) [NOCl] = [NO] D) 2[NO] = [Cl<sub>2</sub>] E) [NO]<sup>2</sup> [Cl<sub>2</sub>] = K<sub>c</sub>[NOCl]<sup>2</sup> 2NO(g) + Cl2(g)


A) [NO] [Cl2] = [NOCl]
B) [NO]2 [Cl2] = [NOCl]2
C) [NOCl] = [NO]
D) 2[NO] = [Cl2]
E) [NO]2 [Cl2] = Kc[NOCl]2

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Consider the following equilibrium, 4NH3(g)+ 3O2(g) Consider the following equilibrium, 4NH<sub>3</sub>(g)+ 3O<sub>2</sub>(g)   <sub> </sub> 2N<sub>2</sub>(g)+ 6H<sub>2</sub>O(g)+ 1531 kJ State whether the concentrations the reactants would increase, decrease, or remain constant after nitrogen gas was removed from the system. 2N2(g)+ 6H2O(g)+ 1531 kJ State whether the concentrations the reactants would increase, decrease, or remain constant after nitrogen gas was removed from the system.

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Hydrogen iodide decomposes according to the equation: 2HI(g) Hydrogen iodide decomposes according to the equation: 2HI(g)   <sub> </sub> <sub> </sub>H<sub>2</sub>(g)+ I<sub>2</sub>(g), K<sub>c</sub> = 0.0156 at 400ºC A 0.660 mol sample of HI was injected into a 2.00 L reaction vessel held at 400ºC. Calculate the concentration of H<sub>2</sub> equilibrium. H2(g)+ I2(g), Kc = 0.0156 at 400ºC A 0.660 mol sample of HI was injected into a 2.00 L reaction vessel held at 400ºC. Calculate the concentration of H2 equilibrium.

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When the following reaction is at equilibrium, which of these relationships is always true? 2 O3(g) When the following reaction is at equilibrium, which of these relationships is always true? 2 O<sub>3</sub>(g)    <sub> </sub> 3 O<sub>2</sub>(g)  A) [O<sub>3</sub>] = [O<sub>2</sub>] B) [O<sub>3</sub>]<sup>2</sup> = [O<sub>2</sub>]<sup>3</sup> C) K<sub>c</sub>[O<sub>3</sub>]<sup>2</sup> = [O<sub>2</sub>]<sup>3</sup> D) K<sub>c</sub>[O<sub>2</sub>]<sup>3</sup> = [O<sub>3</sub>]<sup>2</sup> E) K<sub>c</sub>[O<sub>2</sub>]<sup>2</sup> = [O<sub>3</sub>]<sup>3</sup> 3 O2(g)


A) [O3] = [O2]
B) [O3]2 = [O2]3
C) Kc[O3]2 = [O2]3
D) Kc[O2]3 = [O3]2
E) Kc[O2]2 = [O3]3

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Consider this reaction at equilibrium: 2SO2(g) + O2(g)  Consider this reaction at equilibrium: 2SO<sub>2</sub>(g) + O<sub>2</sub>(g)    <sub> </sub> 2SO<sub>3</sub>(g) ,  \Delta Hº<sub>rxn</sub> = -198 kJ/mol If the volume of the system is compressed at constant temperature, what change will occur in the position of the equilibrium? A) A shift to produce more SO<sub>2</sub> B) A shift to produce more O<sub>2</sub> C) No change D) A shift to produce more SO<sub>3</sub> 2SO3(g) , Δ\Deltarxn = -198 kJ/mol If the volume of the system is compressed at constant temperature, what change will occur in the position of the equilibrium?


A) A shift to produce more SO2
B) A shift to produce more O2
C) No change
D) A shift to produce more SO3

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The equilibrium constant for the reaction Ni(s) + 4CO(g) The equilibrium constant for the reaction Ni(s) + 4CO(g)    <sub> </sub> <sub> </sub>Ni(CO) <sub>4</sub>(g) is 5.0 × 10<sup>4</sup> at 25ºC.What is the equilibrium constant for the reaction Ni(CO) <sub>4</sub>(g) <sub> </sub> <sub> </sub>   <sub> </sub> <sub> </sub>Ni(s) + 4CO(g) ? A) 2.0 × 10<sup>-5</sup> B) 2.5 × 10<sup>9</sup> C) 5.0 × 10<sup>4</sup> D) 5.0 × 10<sup>-4</sup> E) 2.0 × 10<sup>-3</sup> Ni(CO) 4(g) is 5.0 × 104 at 25ºC.What is the equilibrium constant for the reaction Ni(CO) 4(g) The equilibrium constant for the reaction Ni(s) + 4CO(g)    <sub> </sub> <sub> </sub>Ni(CO) <sub>4</sub>(g) is 5.0 × 10<sup>4</sup> at 25ºC.What is the equilibrium constant for the reaction Ni(CO) <sub>4</sub>(g) <sub> </sub> <sub> </sub>   <sub> </sub> <sub> </sub>Ni(s) + 4CO(g) ? A) 2.0 × 10<sup>-5</sup> B) 2.5 × 10<sup>9</sup> C) 5.0 × 10<sup>4</sup> D) 5.0 × 10<sup>-4</sup> E) 2.0 × 10<sup>-3</sup> Ni(s) + 4CO(g) ?


A) 2.0 × 10-5
B) 2.5 × 109
C) 5.0 × 104
D) 5.0 × 10-4
E) 2.0 × 10-3

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Two moles of PCl5 are placed in a 5.0 L container.Dissociation takes place according to the equation PCl5(g) Two moles of PCl<sub>5</sub> are placed in a 5.0 L container.Dissociation takes place according to the equation PCl<sub>5</sub>(g)   <sub> </sub> PCl<sub>3</sub>(g)+ Cl<sub>2</sub>(g).At equilibrium, 0.40 mol of Cl<sub>2</sub> are present.Calculate the equilibrium constant (K<sub>c</sub>)for this reaction under the conditions of this experiment. PCl3(g)+ Cl2(g).At equilibrium, 0.40 mol of Cl2 are present.Calculate the equilibrium constant (Kc)for this reaction under the conditions of this experiment.

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A solution was prepared such that the initial concentrations of Cu2+(aq)and CN-(aq)were 0.0120 M and 0.0400 M, respectively.These ions react according to the following chemical equation A solution was prepared such that the initial concentrations of Cu<sup>2+</sup>(aq)and CN<sup>-</sup>(aq)were 0.0120 M and 0.0400 M, respectively.These ions react according to the following chemical equation    What will be the concentration of CN<sup>-</sup>(aq)at equilibrium? What will be the concentration of CN-(aq)at equilibrium?

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8.4 × 10-7 M

For the nitrogen fixation reaction 3H2(g) + N2(g) For the nitrogen fixation reaction 3H<sub>2</sub>(g) + N<sub>2</sub>(g)    <sub> </sub> 2NH<sub>3</sub>(g) , K<sub>c</sub> = 6.0 × 10<sup>-2</sup> at 500°C.If 0.250 M H<sub>2</sub> and 0.050 M NH<sub>3</sub> are present at equilibrium, what is the equilibrium concentration of N<sub>2</sub>? A) 0.750 M B) 2.7 M C) 0.250 M D) 0.025 M E) 1.85 M 2NH3(g) , Kc = 6.0 × 10-2 at 500°C.If 0.250 M H2 and 0.050 M NH3 are present at equilibrium, what is the equilibrium concentration of N2?


A) 0.750 M
B) 2.7 M
C) 0.250 M
D) 0.025 M
E) 1.85 M

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Consider the chemical reaction 2NH3(g) Consider the chemical reaction 2NH<sub>3</sub>(g)   <sub> </sub> N<sub>2</sub>(g)+ 3H<sub>2</sub>(g).The equilibrium is to be established in a 1.0 L container at 1,000 K, where K<sub>c</sub> = 4.0 × 10<sup>-2</sup>.Initially, 1,220 moles of NH<sub>3</sub>(g)are present.Estimate the equilibrium concentration of H<sub>2</sub>(g). N2(g)+ 3H2(g).The equilibrium is to be established in a 1.0 L container at 1,000 K, where Kc = 4.0 × 10-2.Initially, 1,220 moles of NH3(g)are present.Estimate the equilibrium concentration of H2(g).

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Kp for the reaction CO2(g) + C(s) K<sub>p</sub> for the reaction CO<sub>2</sub>(g) + C(s)    <sub> </sub> 2CO(g) is 1.47 at 727°C.Calculate K<sub>c</sub> at this temperature A) 1.47 B) 121 C) 0.0246 D) 0.0179 E) 87.7 2CO(g) is 1.47 at 727°C.Calculate Kc at this temperature


A) 1.47
B) 121
C) 0.0246
D) 0.0179
E) 87.7

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The equilibrium constant for the chemical equation 2NO(g)+ O2(g) The equilibrium constant for the chemical equation 2NO(g)+ O<sub>2</sub>(g)   <sub> </sub> 2NO<sub>2</sub>(g) is two times the equilibrium constant for the chemical equation NO(g)+ <sup>1</sup>/<sub>2</sub>O<sub>2</sub>(g)   <sub> </sub> NO<sub>2</sub>(g). 2NO2(g) is two times the equilibrium constant for the chemical equation NO(g)+ 1/2O2(g) The equilibrium constant for the chemical equation 2NO(g)+ O<sub>2</sub>(g)   <sub> </sub> 2NO<sub>2</sub>(g) is two times the equilibrium constant for the chemical equation NO(g)+ <sup>1</sup>/<sub>2</sub>O<sub>2</sub>(g)   <sub> </sub> NO<sub>2</sub>(g). NO2(g).

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At 340 K, Kp = 69 for the reaction H2(g) + I2(g) At 340 K, K<sub>p</sub> = 69 for the reaction H<sub>2</sub>(g) + I<sub>2</sub>(g) <sub> </sub> <sub> </sub>   <sub> </sub> 2HI(g) .50.0 g of HI is injected into an evacuated 5.00-L rigid cylinder at 340 K.What is the total pressure inside the cylinder when the system comes to equilibrium? A) 2.60 atm B) 1.76 atm C) 0.424 atm D) 2.18 atm E) 10.9 atm 2HI(g) .50.0 g of HI is injected into an evacuated 5.00-L rigid cylinder at 340 K.What is the total pressure inside the cylinder when the system comes to equilibrium?


A) 2.60 atm
B) 1.76 atm
C) 0.424 atm
D) 2.18 atm
E) 10.9 atm

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