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Choose the diamagnetic species from below.


A) Sn2
B) Br
C) P
D) Cr
E) None of the above is diamagnetic.

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Choose the valence orbital diagram that represents the ground state of Zn.


A) Choose the valence orbital diagram that represents the ground state of Zn. A)    B)    C)    D)    E)
B) Choose the valence orbital diagram that represents the ground state of Zn. A)    B)    C)    D)    E)
C) Choose the valence orbital diagram that represents the ground state of Zn. A)    B)    C)    D)    E)
D) Choose the valence orbital diagram that represents the ground state of Zn. A)    B)    C)    D)    E)
E) Choose the valence orbital diagram that represents the ground state of Zn. A)    B)    C)    D)    E)

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Calculate the wavelength of light emitted from a hydrogen atom when an electron undergoes an n = 8 to n = 4 transmission.


A) 1940 nm
B) 2620 nm
C) 1.245 × 103 nm
D) 3.178 × 103 nm
E) 714.8 nm

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Calculate the energy of the violet light emitted by a hydrogen atom with a wavelength of 410.1 nm.


A) 4.85 × 10-19 J
B) 2.06 × 10-19 J
C) 1.23 × 10-19 J
D) 8.13 × 10-19 J
E) 5.27 × 10-19 J

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Choose the ground-state electron configuration for Ti2⁺.


A) [Ar]3d2
B) [Ar]4s2
C) [Ar]4s23d2
D) [Ar]4s23d4
E) [Ar]3d4

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Determine the velocity of a marble (m = 8.66 g) with a wavelength of 3.46 × 10-33 m.


A) 45.2 m s-1
B) 11.3 m s-1
C) 22.1 m s-1
D) 38.8 m s-1
E) 52.9 m s-1

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Determine the energy change associated with the transition from n = 2 to n = 5 in the hydrogen atom.


A) -2.18 × 10-19 J
B) +6.54 × 10-19 J
C) +4.58 × 10-19 J
D) -1.53 × 10-19 J
E) +3.76 × 10-19 J

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What are the possible orbitals for n = 3?


A) s, p, d
B) s, p, d, f
C) s
D) s, p

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Electromagnetic radiation with a wavelength of 531 nm appears as green light to the human eye. The energy of one photon of this light is 3.74 × 10-19 J. Thus, a laser that emits 1.3 × 10-2 J of energy in a pulse of light at this wavelength produces ________ photons in each pulse.


A) 2.9 × 10-17
B) 9.2 × 10-24
C) 1.8 × 1019
D) 3.5 × 1016
E) 6.5 × 1013

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Identify the set of four quantum numbers that could represent the last electron added (using the aufbau principle) to the Ne atom.


A) n = 3, l = 1, ml = 1, ms = + Identify the set of four quantum numbers that could represent the last electron added (using the aufbau principle) to the Ne atom. A) n = 3, l = 1, m<sub>l</sub> = 1, m<sub>s</sub> = +   B) n = 3, l = 0, m<sub>l</sub> = 1, m<sub>s</sub> = -   C) n = 3, l = 2, m<sub>l</sub> =1 , m<sub>s</sub> = +   D) n = 2, l = 1, m<sub>l</sub> = 1, m<sub>s</sub> = -   E) n = 3, l =2 , m<sub>l</sub> = 1, m<sub>s</sub> = -
B) n = 3, l = 0, ml = 1, ms = - Identify the set of four quantum numbers that could represent the last electron added (using the aufbau principle) to the Ne atom. A) n = 3, l = 1, m<sub>l</sub> = 1, m<sub>s</sub> = +   B) n = 3, l = 0, m<sub>l</sub> = 1, m<sub>s</sub> = -   C) n = 3, l = 2, m<sub>l</sub> =1 , m<sub>s</sub> = +   D) n = 2, l = 1, m<sub>l</sub> = 1, m<sub>s</sub> = -   E) n = 3, l =2 , m<sub>l</sub> = 1, m<sub>s</sub> = -
C) n = 3, l = 2, ml =1 , ms = + Identify the set of four quantum numbers that could represent the last electron added (using the aufbau principle) to the Ne atom. A) n = 3, l = 1, m<sub>l</sub> = 1, m<sub>s</sub> = +   B) n = 3, l = 0, m<sub>l</sub> = 1, m<sub>s</sub> = -   C) n = 3, l = 2, m<sub>l</sub> =1 , m<sub>s</sub> = +   D) n = 2, l = 1, m<sub>l</sub> = 1, m<sub>s</sub> = -   E) n = 3, l =2 , m<sub>l</sub> = 1, m<sub>s</sub> = -
D) n = 2, l = 1, ml = 1, ms = - Identify the set of four quantum numbers that could represent the last electron added (using the aufbau principle) to the Ne atom. A) n = 3, l = 1, m<sub>l</sub> = 1, m<sub>s</sub> = +   B) n = 3, l = 0, m<sub>l</sub> = 1, m<sub>s</sub> = -   C) n = 3, l = 2, m<sub>l</sub> =1 , m<sub>s</sub> = +   D) n = 2, l = 1, m<sub>l</sub> = 1, m<sub>s</sub> = -   E) n = 3, l =2 , m<sub>l</sub> = 1, m<sub>s</sub> = -
E) n = 3, l =2 , ml = 1, ms = - Identify the set of four quantum numbers that could represent the last electron added (using the aufbau principle) to the Ne atom. A) n = 3, l = 1, m<sub>l</sub> = 1, m<sub>s</sub> = +   B) n = 3, l = 0, m<sub>l</sub> = 1, m<sub>s</sub> = -   C) n = 3, l = 2, m<sub>l</sub> =1 , m<sub>s</sub> = +   D) n = 2, l = 1, m<sub>l</sub> = 1, m<sub>s</sub> = -   E) n = 3, l =2 , m<sub>l</sub> = 1, m<sub>s</sub> = -

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The de Broglie wavelength of an electron with a velocity of 6.00 × 106 m s-1 is ________ m. The mass of the electron is 9.11 × 10-28 g.


A) 8.25 × 109
B) 8.25 × 1012
C) 1.21 × 10-16
D) 1.21 × 10-13
E) 1.21 × 10-10

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What is the maximum number of d orbitals that are possible?


A) 1
B) 3
C) 7
D) 5
E) 9

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Calculate the de Broglie wavelength of a pen with a mass of 14.28 g travelling at 16.3 m s-1.


A) 1.76 × 10-31 m
B) 6.43 × 10-37 m
C) 2.85 × 10-33 m
D) 8.19 × 10-32 m
E) 5.30 × 10-34 m

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Choose the ground-state electron configuration for Zr2⁺.


A) [Kr]5s2
B) [Kr]5s24d2
C) [Kr]4d2
D) [Kr]
E) [Kr]5s24d4

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Identify the correct values for a 3p sublevel.


A) n = 3, l = 1, ml = 0
B) n = 2, l = 1, ml = -2
C) n = 1, l = 0, ml = 0
D) n = 2, l = 0, ml = 0
E) n = 4, l = -1, ml = -2

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Calculate the wavelength of an electron (m = 9.11 × 10-28 g) moving at 3.66 × 106 m s-1.


A) 1.99 × 10-10 m
B) 5.03 × 10-10 m
C) 1.81 × 10-10 m
D) 5.52 × 10-9 m
E) 2.76 × 10-9 m

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Calculate the de Broglie wavelength of an egg with a mass of 60 g travelling at 32.18 m s-1.


A) 5.0 × 10-34 m
B) 2.8 × 10-34 m
C) 4.9 × 10-34 m
D) 1.2 × 10-34 m
E) 3.4 × 10-34 m

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What are the possible values of l if n = 6?


A) 6
B) 0, 1, 2, 3, 4, or 5
C) -4, -3, -2, -1, 0, +1, +2, +3, or +4
D) -5, -4, -3, -2, -1, 0, +1, +2, +3, +4, or +5

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The vertical height of a wave is called


A) wavelength.
B) amplitude.
C) frequency.
D) area.
E) median.

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How much energy (in kJ) do 3.0 moles of photons, all with a wavelength of 655 nm, contain?


A) 183 kJ
B) 303 kJ
C) 394 kJ
D) 548 kJ
E) 254 kJ

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