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A reaction with an unfavorable equilibrium constant can be driven to completion by continually removing one of the _____ of the reaction.

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If Q > K, then the ratio of the concentrations of products to the concentrations of reactants is _____ than at equilibrium.

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Explain the relationship between the equilibrium constant and the rate constants for the forward and reverse reactions with an example.

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Consider the decomposition of blured image to NO2, th...

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Kp = K only if the moles of gaseous products and gaseous reactants are different.

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Identify the equilibrium constant expression for the following reaction: 2C8H18( g) +25O2( g) f16CO2( g) +18H2O(g) 2 \mathrm { C } _ { 8 } \mathrm { H } _ { 18 } ( \mathrm {~g} ) + 25 \mathrm { O } _ { 2 } ( \mathrm {~g} ) f \quad 16 \mathrm { CO } _ { 2 } ( \mathrm {~g} ) + 18 \mathrm { H } _ { 2 } \mathrm { O } ( \mathrm { g } )


A) [CO2]16[H2O]18[C8H18]2[O2]25\frac { \left[ \mathrm { CO } _ { 2 } \right] ^ { 16 } \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] ^ { 18 } } { \left[ \mathrm { C } _ { 8 } \mathrm { H } _ { 18 } \right] ^ { 2 } \left[ \mathrm { O } _ { 2 } \right] ^ { 25 } }
B) [CO2]16[H2O]13[C8H18]2[O2]25\left[ \mathrm { CO } _ { 2 } \right] ^ { 16 } \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] ^ { 13 } \left[ \mathrm { C } _ { 8 } \mathrm { H } _ { 18 } \right] ^ { 2 } \left[ \mathrm { O } _ { 2 } \right] ^ { 25 }
C) [CO2]16[H2O]18[C8H18]2[O2]25\left[ \mathrm { CO } _ { 2 } \right] ^ { 16 } \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] ^ { 18 } - \left[ \mathrm { C } _ { 8 } \mathrm { H } _ { 18 } \right] ^ { 2 } \left[ \mathrm { O } _ { 2 } \right] ^ { 25 }
D) [CO2]16[H2O]18+[C8H18]2[O2]25\left[ \mathrm { CO } _ { 2 } \right] ^ { 16 } \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] ^ { 18 } + \left[ \mathrm { C } _ { 8 } \mathrm { H } _ { 18 } \right] ^ { 2 } \left[ \mathrm { O } _ { 2 } \right] ^ { 25 }
E) [C8H18]2[O2]25[CO2]16[H2O]18\frac { \left[ \mathrm { C } _ { 8 } \mathrm { H } _ { 18 } \right] ^ { 2 } - \left[ \mathrm { O } _ { 2 } \right] ^ { 25 } } { \left[ \mathrm { CO } _ { 2 } \right] ^ { 16 } - \left[ \mathrm { H } _ { 2 } \mathrm { O } \right] ^ { 18 } }

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_____ are responsible for the scents associated with fruits such as oranges and bananas.


A) Crown ethers
B) Amalgams
C) Cryptands
D) Esters
E) Catalysts

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_____ control consists of adjusting conditions so that at equilibrium only the desired products are present in significant quantities.

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The altering of reaction conditions so that a single desired product or set of products is present in significant quantities at equilibrium is known as _____ control.


A) potential
B) ionic
C) electrostatic
D) kinetic
E) thermodynamic

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Calculate Kp for the reaction H2(g) +I2(g) f2HI(g) \mathrm { H } _ { 2 } ( g ) + \mathrm { I } _ { 2 } ( g ) f \quad 2 \mathrm { HI } ( g ) . Given that the mixture of H2 and I2 was maintained at 740 K until the system reached equilibrium, and the equilibrium mixture contained 3.68 × 10?2 M HI, 8.31 × 10?3 M H2, and 7.72 × 10?4 M I2.


A) 3.68 × 10?2
B) 2.11 × 102
C) 5.73 × 103
D) 1.74 × 10?4
E) 8.31 × 10?3

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Which of the following is the expression to calculate the equilibrium constant for partial pressures?


A) Kp=(PC) c(PD) d(PA) a(PB) bK _ { \mathrm { p } } = \frac { \left( P _ { \mathrm { C } } \right) ^ { \mathrm { c } } \left( P _ { \mathrm { D } } \right) ^ { \mathrm { d } } } { \left( P _ { \mathrm { A } } \right) ^ { \mathrm { a } } \left( P _ { \mathrm { B } } \right) ^ { \mathrm { b } } }
B) Kp=(PC) c(PD) d+(PA) a(PB) bK _ { \mathrm { p } } = \left( P _ { \mathrm { C } } \right) ^ { \mathrm { c } } \left( P _ { \mathrm { D } } \right) ^ { \mathrm { d } } + \left( P _ { \mathrm { A } } \right) ^ { \mathrm { a } } \left( P _ { \mathrm { B } } \right) ^ { \mathrm { b } }
C) Kp=(PC) c(PD) d(PA) a(PB) bK _ { \mathrm { p } } = \left( P _ { \mathrm { C } } \right) ^ { \mathrm { c } } \left( P _ { \mathrm { D } } \right) ^ { \mathrm { d } } - \left( P _ { \mathrm { A } } \right) ^ { \mathrm { a } } \left( P _ { \mathrm { B } } \right) ^ { \mathrm { b } }
D) KP=(PC) c+(PD) d×(PA) a+(PB) bK _ { \mathrm { P } } = \left( P _ { \mathrm { C } } \right) ^ { \mathrm { c } } + \left( P _ { \mathrm { D } } \right) ^ { \mathrm { d } } \times \left( P _ { \mathrm { A } } \right) ^ { \mathrm { a } } + \left( P _ { \mathrm { B } } \right) ^ { \mathrm { b } }
E) Kp=(PA) a(PB) b(PC) c(PD) dK _ { \mathrm { p } } = \frac { \left( P _ { \mathrm { A } } \right) ^ { \mathrm { a } } - \left( P _ { \mathrm { B } } \right) ^ { \mathrm { b } } } { \left( P _ { \mathrm { C } } \right) ^ { \mathrm { c } } - \left( P _ { \mathrm { D } } \right) ^ { \mathrm { d } } }

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In all reactions, if a _____ is applied to a system at equilibrium, the composition of the system will change to counteract the applied stress.

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If a balanced chemical equation contains different numbers of gaseous reactant and product molecules, the _____ will be sensitive to changes in volume or pressure.

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Which of the following statements refer to the LeChâtelier's Principle?


A) If a stress is applied to a system at equilibrium, the composition of the system will change to relieve the applied stress.
B) The uncertainty in the position of a particle multiplied by the uncertainty in its momentum is greater than or equal to Planck's constant divided by 4π.
C) The energy of electromagnetic radiation is directly proportional to its frequency and inversely proportional to its wavelength.
D) No two electrons in an atom can have the same value of all four quantum numbers.
E) Matter and energy have properties typical of both waves and particles.

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